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  From: Stephen Harding <Steve.Harding@nottingham.ac.uk>
  To  : minton@helix.nih.gov
  Date: Fri, 07 Sep 2001 08:14:30 +0100

Re: hydrodynamic question

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Dear Allen
You can either use formulae for the rod, the latest one I think being the =
Garcia-de la Torre-Tirado one (see eq. 34 of my 1995 review Biophys. Chem. =
55, (1995) 69-93) or use a bead-shell model.  Jose Garcia de la Torre has =
a new programme which both sets up the model and does the calculations =
coupled to HYDRO/SOLPRO so why don't you drop him a line?=20
Remember that unlike for ellipsoids the hydrodynamic equations for beads =
and rods are only approximate - but thanks to the work of the Garcia de la =
Torre team the approximation is generally very good.
Alternatively if the rod is long enough a prolate ellipsoid may suffice
Steve Harding


---------------------------------------------------------------------------=
-------
Professor S.E. Harding
NCMH Physical Biochemistry Laboratory
University of Nottingham
School of Biosciences
Sutton Bonington=20
LE12 5RD, UK
Tel: +44(0) 115-951-6148
Fax: +44(0) 115-951-6142
http://www.nottingham.ac.uk/ncmh/                          =20
---------------------------------------------------------------------------=
------




>>> Allen Minton <minton@helix.nih.gov> 09/06/01 09:41pm >>>
Hi gang -

A question for the hydrodynamics experts:

We can calculate the frictional coefficient for an ellipsoid of rotation=20=

(prolate or oblate) using the well-known Perrin equation.   How can we=20
calculate the frictional coefficient for a cylindrical rod of arbitrary=20
length/diameter ratio?

I am guessing that the bead model might work, but it's not clear how =
one=20
would best represent the rod as an array of beads.  I doubt that one =
could=20
realistically represent the rod as a simple linear array of beads with =
a=20
diameter equal to a bead diameter and a length equal to the number of =
beads=20
times the bead diameter, but perhaps some experienced person could set =
me=20
right on that point.

Does anyone know of an analytical solution to the rod problem, along =
the=20
lines of the Perrin equation?

Allen Minton

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<META http-equiv=3DContent-Type content=3D"text/html; charset=3Diso-8859-1"=
>
<META content=3D"MSHTML 5.50.4134.600" name=3DGENERATOR></HEAD>
<BODY style=3D"MARGIN-TOP: 2px; FONT: 8pt MS Sans Serif; MARGIN-LEFT: =
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<DIV><FONT size=3D1></FONT>Dear Allen<BR>You can either use formulae for =
the rod,=20
the latest one I think being the Garcia-de la Torre-Tirado one (see eq. 34 =
of my=20
1995 review Biophys. Chem. 55, (1995) 69-93) or use a bead-shell model.&nbs=
p;=20
Jose Garcia de la Torre has a new programme which both sets up the model =
and=20
does the calculations coupled to HYDRO/SOLPRO so why don't you drop him a =
line?=20
<BR>Remember that unlike for ellipsoids the hydrodynamic equations for =
beads and=20
rods are only approximate - but thanks to the work of the Garcia de la =
Torre=20
team the approximation is generally very good.</DIV>
<DIV>Alternatively if the rod is long enough a prolate ellipsoid =
may=20
suffice<BR>Steve Harding<BR></DIV>
<DIV> </DIV>
<DIV>----------------------------------------------------------------------=
------------<BR>Professor=20
S.E. Harding<BR>NCMH Physical Biochemistry Laboratory<BR>University of=20
Nottingham<BR>School of Biosciences<BR>Sutton Bonington <BR>LE12 5RD, =
UK<BR>Tel:=20
+44(0) 115-951-6148<BR>Fax: +44(0) 115-951-6142<BR><A=20
href=3D"http://www.nottingham.ac.uk/ncmh/">http://www.nottingham.ac.uk/ncmh=
/</A>           &nbs=
p;            &=
nbsp; =20
<BR>-----------------------------------------------------------------------=
----------</DIV>
<DIV> </DIV>
<DIV><BR><BR><BR>>>> Allen Minton <minton@helix.nih.gov> =
09/06/01=20
09:41pm >>><BR>Hi gang -<BR><BR>A question for the hydrodynamics=
=20
experts:<BR><BR>We can calculate the frictional coefficient for an =
ellipsoid of=20
rotation <BR>(prolate or oblate) using the well-known Perrin=20
equation.   How can we <BR>calculate the frictional coefficient =
for a=20
cylindrical rod of arbitrary <BR>length/diameter ratio?<BR><BR>I am =
guessing=20
that the bead model might work, but it's not clear how one <BR>would =
best=20
represent the rod as an array of beads.  I doubt that one could=20
<BR>realistically represent the rod as a simple linear array of beads with =
a=20
<BR>diameter equal to a bead diameter and a length equal to the number of =
beads=20
<BR>times the bead diameter, but perhaps some experienced person could set =
me=20
<BR>right on that point.<BR><BR>Does anyone know of an analytical solution =
to=20
the rod problem, along the <BR>lines of the Perrin equation?<BR><BR>Allen=
=20
Minton<BR></DIV></BODY></HTML>

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